Amidophenolate Tantalum Complexes

P. A. Petrov; E. A. Golubitskaya; I. V. El’tsov; T. S. Sukhikh; M. N. Sokolov

doi:10.1134/S1070328421090074

Amidophenolate Tantalum Complexes

P. A. Petrov, E. A. Golubitskaya, I. V. El’tsov, T. S. Sukhikh, M. N. Sokolov

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Abstract

Mixed-ligand amidophenolate complexes [Ta(AP^Dipp)(NMe₂)₃] (I) and [Ta(AP^Dipp)₂(NMe₂)] (II) were obtained by the reaction of Ta(NMe₂)₅ with 2,4-di-tert-butyl-6-((2,6-diisopropylphenyl)amino)phenol (H₂AP^Dipp). The products were characterized by X-ray diffraction (CIF file CCDC nos. 2060699 (I), 2060700 (II∙0.5C₅H₁₂)) and NMR spectroscopy.

Original language	English
Pages (from-to)	587-592
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	47
Issue number	9
DOIs	https://doi.org/10.1134/S1070328421090074
Publication status	Published - Sep 2021

Keywords

amidophenolates
amines
tantalum
X-ray diffraction

OECD FOS+WOS

2.04 CHEMICAL ENGINEERING
1.04 CHEMICAL SCIENCES

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title = "Amidophenolate Tantalum Complexes",

abstract = "Mixed-ligand amidophenolate complexes [Ta(APDipp)(NMe2)3] (I) and [Ta(APDipp)2(NMe2)] (II) were obtained by the reaction of Ta(NMe2)5 with 2,4-di-tert-butyl-6-((2,6-diisopropylphenyl)amino)phenol (H2APDipp). The products were characterized by X-ray diffraction (CIF file CCDC nos. 2060699 (I), 2060700 (II∙0.5C5H12)) and NMR spectroscopy.",

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author = "Petrov, {P. A.} and Golubitskaya, {E. A.} and El{\textquoteright}tsov, {I. V.} and Sukhikh, {T. S.} and Sokolov, {M. N.}",

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year = "2021",

month = sep,

doi = "10.1134/S1070328421090074",

language = "English",

volume = "47",

pages = "587--592",

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TY - JOUR

T1 - Amidophenolate Tantalum Complexes

AU - Petrov, P. A.

AU - Golubitskaya, E. A.

AU - El’tsov, I. V.

AU - Sukhikh, T. S.

AU - Sokolov, M. N.

PY - 2021/9

Y1 - 2021/9

N2 - Mixed-ligand amidophenolate complexes [Ta(APDipp)(NMe2)3] (I) and [Ta(APDipp)2(NMe2)] (II) were obtained by the reaction of Ta(NMe2)5 with 2,4-di-tert-butyl-6-((2,6-diisopropylphenyl)amino)phenol (H2APDipp). The products were characterized by X-ray diffraction (CIF file CCDC nos. 2060699 (I), 2060700 (II∙0.5C5H12)) and NMR spectroscopy.

AB - Mixed-ligand amidophenolate complexes [Ta(APDipp)(NMe2)3] (I) and [Ta(APDipp)2(NMe2)] (II) were obtained by the reaction of Ta(NMe2)5 with 2,4-di-tert-butyl-6-((2,6-diisopropylphenyl)amino)phenol (H2APDipp). The products were characterized by X-ray diffraction (CIF file CCDC nos. 2060699 (I), 2060700 (II∙0.5C5H12)) and NMR spectroscopy.

KW - amidophenolates

KW - amines

KW - tantalum

KW - X-ray diffraction

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DO - 10.1134/S1070328421090074

M3 - Article

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VL - 47

SP - 587

EP - 592

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 9

ER -

Amidophenolate Tantalum Complexes

Abstract

Keywords

OECD FOS+WOS

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