Abstract
The catalytic activity of the SBA-15-supported silver and/or ceria catalysts in the 4‑nitrophenol reduction under mild conditions is described. The catalysts are prepared by wetness impregnation of Pluronic P123@SBA-15 hybrid applied to stabilize small Ag and CeO2 particles. The bare SBA-15 and the catalysts on the basis thereof are characterized by N2 sorption, XRD, SAXS, TEM, UV–vis DRS, and H2-TPR. The catalysts possess high surface area (594−754 m2/g) and narrow pore size distributions (5.5–7.8 nm). Silver and ceria particles are stabilized in a highly dispersed state (predominant sizes below 5 nm) in the ordered SBA-15 structure. The Ag–CeO2/SBA-15 catalyst demonstrates the presence of the developed Ag–CeO2 interface that enhances the catalytic activity in 4-nitrophenol reduction to 4‑aminophenol (k = 0.016 s−1) at room temperature and ambient pressure due to the cooperation of silver and ceria active sites.
Original language | English |
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Pages (from-to) | 576-584 |
Number of pages | 9 |
Journal | Catalysis Today |
Volume | 375 |
Early online date | 7 May 2020 |
DOIs | |
Publication status | Published - 1 Sep 2021 |
Keywords
- 4-nitrophenol reduction
- Ag–CeO catalysts
- mild conditions
- Pluronic P123@SBA-15 hybrid
- SBA-15
OECD FOS+WOS
- 1.04 CHEMICAL SCIENCES