Activation Parameters of Self-Diffusion of Aromatic Chiral Molecules in External Magnetic Fields

Research output: Contribution to journalArticlepeer-review

Abstract

The mobility of aromatic chiral molecules 1-phenylethanol and 1-phenyl-1-propanol in liquids was studied by 1H NMR spectroscopy depending on the strength of the external magnetic field, temperature, and concentration ratio of enantiomers. The data obtained were analyzed using Arrhenius law. The activation parameters were found to depend on the applied field. This effect is caused by the induced magnetic moments in aromatic molecules. The use of strong magnetic fields seems to be promising for investigation of intermolecular interactions of chiral molecules.

Original languageEnglish
Pages (from-to)6655-6658
Number of pages4
JournalJournal of Physical Chemistry B
Volume121
Issue number27
DOIs
Publication statusPublished - 13 Jul 2017

Keywords

  • NMR-SPECTROSCOPY
  • GLYCEROL
  • MAGNETIZABILITIES
  • COEFFICIENTS
  • COMPLEXES
  • MIXTURES
  • MOBILITY
  • BINARY

Fingerprint Dive into the research topics of 'Activation Parameters of Self-Diffusion of Aromatic Chiral Molecules in External Magnetic Fields'. Together they form a unique fingerprint.

Cite this