A single-crystal to single-crystal phase transition in [Co(NH3)5NO2]Br2 at high pressure: A step towards understanding linkage photo-isomerisation

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Abstract

Changes in the crystal structure of [Co(NH3)5NO2]Br2-including a previously unknown single-crystal to single-crystal phase transition above 6.0 GPa-were followed from ambient pressure to 6.9 GPa and discussed in relation to the structural mechanism of homogeneous linkage photoisomerisation that is accompanied by photomechanical effects in the same compound.

Original languageEnglish
Pages (from-to)8812-8816
Number of pages5
JournalCrystEngComm
Volume17
Issue number46
DOIs
Publication statusPublished - 2015

OECD FOS+WOS

  • 1.04.FI CRYSTALLOGRAPHY
  • 1.04 CHEMICAL SCIENCES

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