A new family of clusters containing a silver-centered tetracapped [Ag@Ag43-P)4] tetrahedron, inscribed within a N12 icosahedron

Alexander V. Artem'Ev, Irina Yu Bagryanskaya, Evgeniya P. Doronina, Peter M. Tolstoy, Artem L. Gushchin, Mariana I. Rakhmanova, Alexander Yu Ivanov, Anastasiya O. Suturina

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

An unprecedented silver-centered P-tetracapped [Ag@Ag43-P)4] tetrahedron inscribed within a N12 icosahedral cage has been discovered in the novel family of luminescent clusters. The latter are easily self-assembled by reacting AgI salts with tris(2-pyridyl)phosphine (Py3P).

Original languageEnglish
Pages (from-to)12425-12429
Number of pages5
JournalDalton Transactions
Volume46
Issue number37
DOIs
Publication statusPublished - 26 Sep 2017

Keywords

  • LUMINESCENT GOLD(I)-SILVER(I) CLUSTER
  • CHALCOGENIDE CLUSTERS
  • COMPLEXES
  • COORDINATION
  • PHOSPHINE

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