Abstract
A reaction of a [1,4-C6H4(CH2PPy3)2]Cl2 cationic ligand with CuI (MeCN, r.t.) produces an ionic [C6H4(CH2PPy3)2][C6H4(CH2PPy3Cu3I5)2] complex containing structurally unprecedented [Cu3I5]2– inorganic module in the anionic part. The title complex in the solid manifests a weak deep-red luminescence with λmax = 680 nm and lifetimes of 14 μs and 17 μs at 300 K and 77 K, respectively.
Original language | English |
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Pages (from-to) | 1068-1071 |
Number of pages | 4 |
Journal | Journal of Structural Chemistry |
Volume | 61 |
Issue number | 7 |
DOIs | |
Publication status | Published - 1 Jul 2020 |
Keywords
- crystal structure
- Cu(I) complexes
- iodocuprates
- photoluminescence
- pyridylphosphonium salts
OECD FOS+WOS
- 1.04 CHEMICAL SCIENCES