Abstract
The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.
Original language | English |
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Pages (from-to) | 279-283 |
Number of pages | 5 |
Journal | Journal of Structural Chemistry |
Volume | 60 |
Issue number | 2 |
DOIs | |
Publication status | Published - 1 Feb 2019 |
Keywords
- chiral complexes
- coordination polymers
- copper(II) complexes
- crystal structure
- malic acid