A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

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5 Citations (Scopus)

Abstract

The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

Original languageEnglish
Pages (from-to)279-283
Number of pages5
JournalJournal of Structural Chemistry
Volume60
Issue number2
DOIs
Publication statusPublished - 1 Feb 2019

Keywords

  • chiral complexes
  • coordination polymers
  • copper(II) complexes
  • crystal structure
  • malic acid

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