A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

M. S. Zavakhina; D. G. Samsonenko; V. P. Fedin

doi:10.1134/S0022476619020136

A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

M. S. Zavakhina, D. G. Samsonenko, V. P. Fedin

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The [Cu ₈ (S-mal) ₄ (bptc)(H ₂ O) ₁₂ ] · 0.5H ₄ bptc · 7.5H ₂ O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H ₃ mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H ₄ bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

Original language	English
Pages (from-to)	279-283
Number of pages	5
Journal	Journal of Structural Chemistry
Volume	60
Issue number	2
DOIs	https://doi.org/10.1134/S0022476619020136
Publication status	Published - 1 Feb 2019

Keywords

chiral complexes
coordination polymers
copper(II) complexes
crystal structure
malic acid

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10.1134/S0022476619020136

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title = "A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid",

abstract = " The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis. ",

keywords = "chiral complexes, coordination polymers, copper(II) complexes, crystal structure, malic acid",

author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

year = "2019",

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T1 - A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

AB - The [Cu 8 (S-mal) 4 (bptc)(H 2 O) 12 ] · 0.5H 4 bptc · 7.5H 2 O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H 3 mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H 4 bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

KW - chiral complexes

KW - coordination polymers

KW - copper(II) complexes

KW - crystal structure

KW - malic acid

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