8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene

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Abstract

During recent years, the BODIPY core became a popular scaffold for designing photo-removable protecting groups (PPG). In this paper, we report the synthesis of a new mole-cule—8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐boron‐3a,4a‐diaza‐S‐indacene —by the treatment of meso‐(4‐CO2Me‐phenyl)‐BODIPY with excess of MeMgI. The product was characterized by1H,13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG.

Original languageEnglish
Article numberM1286
JournalMolBank
Volume2021
Issue number4
DOIs
Publication statusPublished - Dec 2021

Keywords

  • BODIPY
  • Methylmagnesium iodide
  • Photoremovable protecting group
  • Tertiary alcohol

OECD FOS+WOS

  • 1.06 BIOLOGICAL SCIENCES
  • 1.04 CHEMICAL SCIENCES

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