2-Chlorobenzoate Complex of Cu(II): Unexpected Appearance of Halogen···Halogen Contacts in Solid State

Sergey A. Adonin, Mikhail D. Petrov, Alexander S. Novikov, Rishat R. Shiriyazdanov, Maxim N. Sokolov, Vladimir P. Fedin

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Abstract

Complex of copper [Cu 2 (2-ClBenz) 4 ((acetone) 2 ] (2-ClBenz = 2-chlorobenzoate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via Cl···Cl contacts (3.440 Å); their energies were estimated by theoretical methods.

Original languageEnglish
Pages (from-to)857-861
Number of pages5
JournalJournal of Cluster Science
Volume30
Issue number4
DOIs
Publication statusPublished - 15 Jul 2019

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Keywords

  • Carboxylate complexes
  • Copper
  • Crystal structure
  • Halogen bonding
  • Supramolecular contacts
  • CARBOXYLATE BRIDGES
  • S-ALKYL DERIVATIVES
  • MOLECULAR-STRUCTURE
  • BINUCLEAR COPPER(II) COMPLEXES
  • PYRIDINE
  • X-RAY-STRUCTURE
  • ACID. CRYSTAL-STRUCTURE
  • COORDINATION POLYMERS
  • METAL-IONS
  • BOND

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