Abstract
Three novel polybromotellurates(IV) were obtained by reactions of TeO2 in conc. HBr with Br2 and tri- or tetraalkylammonium salts. They contain [TeBr6]2– octahedra connected by {Br2} linkers into one- or pseudo-two-dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).
Original language | English |
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Pages (from-to) | 3264-3269 |
Number of pages | 6 |
Journal | European Journal of Inorganic Chemistry |
Volume | 2018 |
Issue number | 27 |
DOIs | |
Publication status | Published - 23 Jul 2018 |
Keywords
- Noncovalent interactions
- Polyhalides
- QTAIM
- Tellurium