1D and 2D Polybromotellurates(IV): Structural Studies and Thermal Stability

Andrey N. Usoltsev; Sergey A. Adonin; Pavel A. Abramov; Alexander S. Novikov; Vladimir R. Shayapov; Pavel E. Plyusnin; Ilya V. Korolkov; Maxim N. Sokolov; Vladimir P. Fedin

doi:10.1002/ejic.201800383

1D and 2D Polybromotellurates(IV): Structural Studies and Thermal Stability

Andrey N. Usoltsev, Sergey A. Adonin, Pavel A. Abramov, Alexander S. Novikov, Vladimir R. Shayapov, Pavel E. Plyusnin, Ilya V. Korolkov, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Three novel polybromotellurates(IV) were obtained by reactions of TeO₂ in conc. HBr with Br₂ and tri- or tetraalkylammonium salts. They contain [TeBr₆]^2– octahedra connected by {Br₂} linkers into one- or pseudo-two-dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).

Original language	English
Pages (from-to)	3264-3269
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Volume	2018
Issue number	27
DOIs	https://doi.org/10.1002/ejic.201800383
Publication status	Published - 23 Jul 2018

Keywords

Noncovalent interactions
Polyhalides
QTAIM
Tellurium

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10.1002/ejic.201800383

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@article{29d125e8541046428cf4816e95f1b439,

title = "1D and 2D Polybromotellurates(IV): Structural Studies and Thermal Stability",

abstract = "Three novel polybromotellurates(IV) were obtained by reactions of TeO2 in conc. HBr with Br2 and tri- or tetraalkylammonium salts. They contain [TeBr6]2– octahedra connected by {Br2} linkers into one- or pseudo-two-dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).",

keywords = "Noncovalent interactions, Polyhalides, QTAIM, Tellurium",

author = "Usoltsev, {Andrey N.} and Adonin, {Sergey A.} and Abramov, {Pavel A.} and Novikov, {Alexander S.} and Shayapov, {Vladimir R.} and Plyusnin, {Pavel E.} and Korolkov, {Ilya V.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

year = "2018",

month = jul,

day = "23",

doi = "10.1002/ejic.201800383",

language = "English",

volume = "2018",

pages = "3264--3269",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "27",

}

1D and 2D Polybromotellurates(IV) : Structural Studies and Thermal Stability. / Usoltsev, Andrey N.; Adonin, Sergey A.; Abramov, Pavel A.; Novikov, Alexander S.; Shayapov, Vladimir R.; Plyusnin, Pavel E.; Korolkov, Ilya V.; Sokolov, Maxim N.; Fedin, Vladimir P.

In: European Journal of Inorganic Chemistry, Vol. 2018, No. 27, 23.07.2018, p. 3264-3269.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - 1D and 2D Polybromotellurates(IV)

T2 - Structural Studies and Thermal Stability

AU - Usoltsev, Andrey N.

AU - Adonin, Sergey A.

AU - Abramov, Pavel A.

AU - Novikov, Alexander S.

AU - Shayapov, Vladimir R.

AU - Plyusnin, Pavel E.

AU - Korolkov, Ilya V.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2018/7/23

Y1 - 2018/7/23

N2 - Three novel polybromotellurates(IV) were obtained by reactions of TeO2 in conc. HBr with Br2 and tri- or tetraalkylammonium salts. They contain [TeBr6]2– octahedra connected by {Br2} linkers into one- or pseudo-two-dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).

AB - Three novel polybromotellurates(IV) were obtained by reactions of TeO2 in conc. HBr with Br2 and tri- or tetraalkylammonium salts. They contain [TeBr6]2– octahedra connected by {Br2} linkers into one- or pseudo-two-dimensional networks. The thermal stability of the products was investigated by TGA; additionally, all compounds were characterized by Raman spectroscopy. Energies of Br···Br interactions were estimated by DFT calculations (QTAIM method).

KW - Noncovalent interactions

KW - Polyhalides

KW - QTAIM

KW - Tellurium

UR - http://www.scopus.com/inward/record.url?scp=85050405537&partnerID=8YFLogxK

U2 - 10.1002/ejic.201800383

DO - 10.1002/ejic.201800383

M3 - Article

AN - SCOPUS:85050405537

VL - 2018

SP - 3264

EP - 3269

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 27

ER -

1D and 2D Polybromotellurates(IV): Structural Studies and Thermal Stability

Abstract

Keywords

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