1,1-Difluoronaphthalen-2(1H)-ones as building blocks for fluorinated tetraphenes

Ok Ton Dyan, Pavel A. Zaikin, Dmitry S. Fadeev, Yuri V. Gatilov, Gennady I. Borodkin

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

1,1-Difluoronaphthalen-2(1H)-ones were used as building blocks for synthesis of functionalized fluorinated tetraphenones via Diels-Alder reaction. Two effective methods of tetraphenone reductive aromatization were proposed. Fully aromatic stable fluorinated tetraphene derivative with high solubility and HOMO-LUMO gap of 3.08 eV was obtained.

Original languageEnglish
Pages (from-to)88-93
Number of pages6
JournalJournal of Fluorine Chemistry
Volume210
DOIs
Publication statusPublished - 1 Jun 2018

Keywords

  • Diels-Alder cycloaddition
  • Organofluorine compounds
  • Polycyclic aromatic hydrocarbons

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