Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate

V. S. Gusarov, A. M. Cheplakova, D. G. Samsonenko, A. S. Vinogradov, V. P. Fedin

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction between equimolar amounts of Cd(OH)2 and octafluorobiphenyl-4,4'-dicarboxylic acid H2oFBPDC in methanol at 40 and 70°С has been investigated. Two new metal-organic coordination polymers have been obtained and structurally characterized, namely chain-like [Cd3(CH3OH)10(oFBPDC)3]⋅2CH3OH (I) and layered [Cd(CH3OH)3(oFBPDC)] (II). It is shown that the increase of the temperature of the synthesis leads to the formation of coordination polymer of higher dimensionality with less amount of guest and coordinated solvent molecules.

Translated title of the contributionСинтез и кристаллическая структура металл-органических координационных полимеров на основе Cd(II) и октафторбифенил-4,4'-дикарбоксилата
Original languageEnglish
Article number7
Pages (from-to)1374-1379
Number of pages6
JournalRussian Journal of Inorganic Chemistry
Volume66
Issue number9
DOIs
Publication statusPublished - Sep 2021

Keywords

  • cadmium complexes
  • crystal structure
  • metal-organic coordination polymer
  • octafluorobiphenyl-4,4'-dicarboxylic acid

OECD FOS+WOS

  • 2.05 MATERIALS ENGINEERING
  • 1.04 CHEMICAL SCIENCES

State classification of scientific and technological information

  • 31 CHEMISTRY

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