Рентгеноспектральное изучение электронного строения неинноцентных моно- и биядерных комплексов платины с N-фенил-о-бензосемихинондиимином

Translated title of the contribution: An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine

T. M. Ivanova, Alexey A. Sidorov, Лев Николаевич Мазалов, A. D. Fedorenko, Mikhail A. Kiskin, S. V. Savilov, V. Lunin, V. M. Novotortsev, Igor L. Eremenko, Alexander V. Kalinkin, Юлия Владимировна Федосеева, Александр Владимирович Окотруб

Research output: Contribution to journalArticlepeer-review

Abstract

The electronic structure of mono- and binuclear platinum complexes with N-phenyl-o benzosemiquinondiimine ligands was studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and the density functional theory. The oxidation state of the central platinum ion corresponds to that of Pt(II). Upon the transition from the trans-complex 1 to the cis-complex 2 and to the binuclear complex 3, the electron density on platinum and nitrogen atoms decreases thus testifying the participation of platinum and nitrogen atoms in the oxidation processes and in the formation of binuclear complex 3.
Translated title of the contributionAn X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine
Original languageRussian
Pages (from-to)948-958
Number of pages11
Journal Журнал структурной химии
Volume60
Issue number6
DOIs
Publication statusPublished - 2019

OECD FOS+WOS

  • 1.04 CHEMICAL SCIENCES

State classification of scientific and technological information

  • 31 CHEMISTRY

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